The following determinations,

before and after the interesterification reactions, were done: fatty acid composition, softening point, melting point, solid fat content and consistency. For the analytical responses a multiple regression statistical model was applied. This study has shown that blending and chemical interesterifications are an effective way to modify the physical and chemical properties of palm stearin, palm olein and their blends. The mixture and chemical interesterification allowed obtaining fats with various degrees of plasticity, increasing the possibilities for the commercial use of palm stearin and palm olein. Birinapant mw (C) 2009 Elsevier Ltd. All rights reserved.”
“This work was performed to relate the morphological

features and all important properties of the natural rubber (NR) and bromobutyl rubber (BIIR) blends containing hybrid fillers. The BUR content was varied from 0 to 100 wt%. It is found that tensile and tear strength, hardness as well as resilience of blends tend to decrease with increasing BIIR loading. Regarding the blend morphology, phase inversion is observed when BIIR loading is >50 wt% where BIIR becomes a continuous phase. This result coincides with the marked improvement of thermal stability of the blends determined using thermogravimetric analysis and heat ageing method. Interestingly, that, the gas permeability of blends markedly reduces with an increase in BIIR loading up to 40 wt% when the relatively large elongated particles of BIIR dispersed phase is formed. The results indicate that the relatively large

MLN2238 ic50 connected structure of the dispersed BIIR can act effectively as a gas barrier. (C) 2009 Wiley Periodicals, Inc. J Appl see more Polym Sci 113: 3985-3992, 2009″
“Maillard reaction along with caramelisation are the main chemical reactions occurring in bakery products. They are referred to as non enzymatic browning. In this work, the effect of flour type (wheat rye, and whole-wheat flours) and process conditions were investigated by using a bread crisp model system made up of flour, water and yeast. The bread was toasted at different temperature for different times. In a second set of experiments several additives (glycine, 0.1% on flour; asparaginase, 2000 U kg(-1) of flour and an antioxidant extract from green tea) were added to the basic formulations in order to test their ability in reducing the formation of potentially harmful Maillard reaction compounds such as HMF and acrylamide. Browning development and water content along with antioxidant activity were also monitored.

Rye model systems produced more HMF and acrylamide at all temperature tested, while wholewheat systems produced less HMF, but more acrylamide than wheat one. The addition of glycine was effective in reducing acrylamide formation, and it increased browning development, antioxidant activity and HMF formation.